dc.contributor | Universidade Estadual Paulista (Unesp) | |
dc.date.accessioned | 2014-05-27T11:18:17Z | |
dc.date.available | 2014-05-27T11:18:17Z | |
dc.date.created | 2014-05-27T11:18:17Z | |
dc.date.issued | 1997-11-14 | |
dc.identifier | Journal of Alloys and Compounds, v. 262-263, p. 296-298, 1997 | |
dc.identifier | 0925-8388 | |
dc.identifier | http://hdl.handle.net/11449/65227 | |
dc.identifier | 10.1016/S0925-8388(97)00407-6 | |
dc.identifier | WOS:000071209700058 | |
dc.identifier | 2-s2.0-0031273322 | |
dc.identifier | 2998503841917815 | |
dc.identifier | 3349586880746735 | |
dc.description.abstract | A new modification of scandium fluoride has been synthesised. The compound is deficient in fluorine, with the composition ScF2.76. It belongs to the tetragonal system, lattice parameters being a = 3.792 and c = 6.740 Å and may be obtained at low temperatures by the decomposition of the precursor NH4ScF4. The reaction is topotactic, tetragonal parameters of the precursor are a = 4.021 and c = 6.744 Å. Structural relationships with various fluorides and ammonium aminofluorides are discussed. This synthesis route with IR-assisted decomposition should be considered as a soft-chemistry approach. © 1997 Elsevier Science S.A. | |
dc.language | eng | |
dc.relation | Journal of Alloys and Compounds | |
dc.relation | 3.779 | |
dc.relation | 1,020 | |
dc.rights | Acesso restrito | |
dc.source | Scopus | |
dc.subject | Fiber glasses | |
dc.subject | Fluorides | |
dc.subject | Scandium | |
dc.subject | Ammonium compounds | |
dc.subject | Crystal structure | |
dc.subject | Decomposition | |
dc.subject | Fluorine | |
dc.subject | Lattice constants | |
dc.subject | Modification | |
dc.subject | Synthesis (chemical) | |
dc.subject | Ammonium aminofluoride | |
dc.subject | Scandium fluoride | |
dc.subject | Scandium compounds | |
dc.title | Scandium fluorides | |
dc.type | Artículos de revistas | |