dc.creatorAlves, Fernanda Rosa
dc.creatorLoh, Watson
dc.date2012-Feb
dc.date2015-11-27T13:29:16Z
dc.date2015-11-27T13:29:16Z
dc.date.accessioned2018-03-29T01:16:52Z
dc.date.available2018-03-29T01:16:52Z
dc.identifierJournal Of Colloid And Interface Science. v. 368, n. 1, p. 292-300, 2012-Feb.
dc.identifier1095-7103
dc.identifier10.1016/j.jcis.2011.11.020
dc.identifierhttp://www.ncbi.nlm.nih.gov/pubmed/22172692
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/200398
dc.identifier22172692
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1300631
dc.descriptionThe effect of a polymeric counterion on the thermotropic behavior of sonicated vesicles formed by complex salts in aqueous solution and with decanol (C(10)OH) and tetradecanol (C(14)OH) was investigated. The complex salts were prepared with dioctadecyldimethylammonium bromide (DODAB) and polyacrylic acids (PAA, containing 30 or 6000 repeating units), being referred to as DODAPA(30) and DODAPA(6000). Vesicles containing polymeric counterions presented higher contents of multilamellar vesicles that were dependent on the complex salt concentration and on the counterion chain length. For comparison, studies were performed with DODAAc, with the counterion acetate, resulting in the formation of mostly unilamellar vesicles, as expected due greater dissociation, leading to greater electrical repulsion between bilayers. Mixtures of these complex salts and DODAX (where X=acetate or bromide) were also investigated with respect to their vesicles thermotropic behavior and size. This study opens the possibility of applying the methodology of direct complex salt preparation (as opposed to mixing the surfactant and polymeric components) to produce vesicles with controlled composition and properties.
dc.description368
dc.description292-300
dc.languageeng
dc.relationJournal Of Colloid And Interface Science
dc.relationJ Colloid Interface Sci
dc.rightsfechado
dc.rightsCopyright © 2011 Elsevier Inc. All rights reserved.
dc.sourcePubMed
dc.subjectAcrylic Resins
dc.subjectMembranes, Artificial
dc.subjectQuaternary Ammonium Compounds
dc.subjectSurface-active Agents
dc.titleVesicles Prepared With The Complex Salts Dioctadecyldimethylammonium Polyacrylates.
dc.typeArtículos de revistas


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