Artigo
Efficient reduction of nitrobenzene into aniline using Fe-rich waste from electric furnace dust
Registro en:
PAULA, L. N. de et al. Efficient reduction of nitrobenzene into aniline using Fe-rich waste from electric furnace dust. Environmental Chemistry Letters, [S. l.], v. 13, n. 3, p. 347-351, Sept. 2015.
Autor
Paula, Leandro Neves de
Giusto, Luana Aparecida dos Reis
Ardisson, José Domingos
Magalhães, Fabiano
Institución
Resumen
Nitroaromatic compounds are widely used in the industry. They are most often resistant to microbial degradation, mutagenic and carcinogenic. As a consequence, reduction of nitroaromatic compounds into less toxic and biodegradable products has been studied using Fe0. Here, we tested iron-rich waste from electric furnace dust to convert nitrobenzene into aniline. Thermal reduction of electric furnace dust under hydrogen at 500 °C gave a material with about 56 % Fe0 and 21 % FeO. This material allowed to decrease 86 % of nitrobenzene during the conversion of nitrobenzene into aniline. In conclusion, electric arc furnace dust can be transformed into an efficient reducing reagent.