Artigo de peri??dico
Revisiting electrocatalytic CO2 reduction in nonaqueous media
Registro en:
2194-4288
6
11
10.1002/ente.202201367
0000-0002-5972-5933
37.8
75.00
Autor
REIS, EDUARDO A. dos
SILVA, GELSON T.S.T. da
SANTIAGO, ELISABETE I.
RIBEIRO, CAUE
Resumen
Electrochemical CO2 reduction to fuels or commodity chemicals using renewable
energy has drawn attention as a strategy for closing the anthropogenic chemical
carbon cycle. More than that, enhancing the C???C coupling between the intermediates could lead to producing a range of high-value multi-carbon molecules.
Although the research mainly focuses on the aqueous media for the electrochemical CO2 reduction reaction (eRRCO2), using nonaqueous electrolytes has the
advantage of suppressing the hydrogen evolution reaction, controlling the protonassisted reduction reactions, and favoring the C???C coupling. Herein, the use of
nonaqueous electrolytes for eRRCO2 and the components of the electrochemical
reactor that affect the selectivity of the reaction are revisited. This review provides
a perspective view of recent findings compared to well-established papers while
presenting what is known about eRRCO2 in nonaqueous media. Funda????o de Amparo ?? Pesquisa do Estado de S??o Paulo (FAPESP) Conselho Nacional de Desenvolvimento Cient??fico e Tecnol??gico (CNPq) FAPESP: 14/50279-4; 20/15230-5; #18/01258-5; #22/10255-5 CNPq: 001