Artigo de peri??dico
Development of Y-TZP/MWCNT-SiO2 nanocomposite for dental protheses
Registro en:
1751-6161
143
10.1016/j.jmbbm.2023.105888
0000-0001-7384-304X
47.9
70.33
Autor
SILVA, LUCAS H. da
RINALDI, LAURA A.
LAZAR, DOLORES R.R.
USSUI, VALTER
TANGO, RUBENS N.
BELLI, RENAN
LOHBAUER, ULRICH
CESAR, PAULO F.
Resumen
Y-TZP/MWCNT-SiO2 nanocomposite was synthesized by co-precipitation and hydrothermal treatment methods.
After the characterization of the MWCNT-SiO2 powder, specimens were obtained from the synthesized material
Y-TZP/MWCNT-SiO2 by uniaxial pressing for a second characterization and later comparison of its optical and
mechanical properties with the conventional Y-TZP. The MWCNT-SiO2 was presented in bundles of carbon
nanotubes coated by silica (mean length: 5.10 ?? 1.34 ??m /D90: 6.9 ??m). The composite manufactured was
opaque (contrast ratio: 0.9929 ?? 0.0012) and had a white color with a slightly difference from the conventional
Y-TZP (??E00: 4.4 ?? 2.2) color. The mechanical properties of Y-TZP/MWCNT-SiO2: vickers hardness (10.14 ??
1.27 GPa; p = 0.25) and fracture toughness (4.98 ?? 0.30 MPa m1/2; p = 0.39), showed no significant difference
from the conventional Y-TZP (hardness: 8.87 ?? 0.89; fracture toughness: 4.98 ?? 0.30 MPa m1/2). However, for
flexural strength (p = 0.003), a lower value was obtained for Y-TZP/MWCNT-SiO2 (299.4 ?? 30.5 MPa) when
compared to the control Y-TZP (623.7 ?? 108.8 MPa). The manufactured Y-TZP/MWCNT-SiO2 composite presented satisfactory optical properties, however the co-precipitation and hydrothermal treatment methods need to
be optimized to avoid the formation of porosities and strong agglomerates, both from Y-TZP particles and
MWCNT-SiO2 bundles, which lead to a significant decrease in the material flexural strength. Funda????o de Amparo ?? Pesquisa do Estado de S??o Paulo (FAPESP) FAPESP: 12/10955-5; 13/00728-4; 12/16027-2