Convers??o de metano em metanol com co-gera????o de energia el??trica a partir de catalisadores de pal??dio suportados em carbono

Conversion of methane to methanol with co-generation of electricity from palladium catalysts supported in carbon

dc.creatorSILVA, ARACELI J.
dc.creatorZAMBIAZI, PRISCILLA J.
dc.creatorGOMES, PAULO V.R.
dc.creatorNANDENHA, JULIO
dc.creatorGODOI, CAMILA M.
dc.creatorSOUZA, RODRIGO F.B. de
dc.creatorNETO, ALMIR O.
dc.creatorAZEREDO, NATHALIA F.B.
dc.date2023
dc.date2023-05-18T12:38:43Z
dc.date2023-05-18T12:38:43Z
dc.date.accessioned2023-09-28T14:26:01Z
dc.date.available2023-09-28T14:26:01Z
dc.identifier1984-6835
dc.identifierhttp://repositorio.ipen.br/handle/123456789/34056
dc.identifier2
dc.identifier15
dc.identifier10.21577/1984-6835.20220101
dc.identifier0000-0001-8745-3421
dc.identifierSem Percentil
dc.identifier12
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/9004265
dc.descriptionThe application of solid electrolyte reactors for methane oxidation and energy co-generation is attractive, especially with the use of catalysts synthesized from noble metals such as palladium. In this work, we prepared three different compositions of palladium on carbon support to evaluate the composition that had the greatest potential for energy generation. Catalysts in the proportions of 5, 10 and 20% of Pd/C were tested for the conversion of greenhouse gases into organic molecules of higher added value using electrochemical fuel cell solid electrolyte reactors. The focus of this work was the conversion of methane into methanol, using the fuel cell as a reactor and the commercial Pd/C as electrocatalyst. The electrocatalysts were tested at the anode, analyzed by infrared (IR) spectroscopy and their activities verified by experiments with rotating ring disk electrode (RRDE). Higher levels of palladium (Pd/C 20%) favored obtaining electrical power, and the intermediate composition (Pd/C 10%) showed a greater production of less oxidized compounds, such as methanol, in addition to generating electricity.
dc.descriptionConselho Nacional de Desenvolvimento Cient??fico e Tecnol??gico (CNPq)
dc.descriptionFunda????o de Amparo ?? Pesquisa do Estado de S??o Paulo (FAPESP)
dc.descriptionCNPq: 302709/2020-7
dc.descriptionFAPESP: 17/11937-4
dc.format221-226
dc.relationRevista Virtual de Qu??mica
dc.rightsopenAccess
dc.subjectmethane
dc.subjectoxidation
dc.subjectpalladium
dc.subjectcatalysts
dc.subjectfuel cells
dc.titleConvers??o de metano em metanol com co-gera????o de energia el??trica a partir de catalisadores de pal??dio suportados em carbono
dc.titleConversion of methane to methanol with co-generation of electricity from palladium catalysts supported in carbon
dc.typeArtigo de peri??dico
dc.coverageI


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