Artigo de peri??dico
Analytical expressions for electrochemical supercapacitor with potential dependent capacitance
Registro en:
2352-152X
43
10.1016/j.est.2021.103156
81.09
82.67
Autor
FERNANDEZ, A.P.R.
PERIGO, E.A.
FARIA, R.N.
Resumen
Distinctly from ordinary capacitors which have a fixed capacitance, the capacitance of electrochemical supercapacitors is dependent on the applied potential. This feature introduces an additional complication to the analytical solution representing the supercapacitor circuit. Here a simplified equivalent circuit of electric double layer capacitors or electrochemical supercapacitors is proposed so that expressions evaluating the potential-dependent capacitance are derived considering short periods of charging and discharging process as in cyclic voltammetry carried out in a few minutes. Comparisons between such theoretical development and experimental cyclic voltammetry data ??? presenting a very good agreement ??? are presented and discussed.