Artigo de peri??dico
Anodic layers based on doped-Ceria/Ni cermet for direct ethanol fuel cells
Registro en:
1938-6737
1
78
10.1149/07801.1437ecst
Autor
SILVA, A.A. da
TABUTI, F.N.
MATTOS, L.V.
STEIL, M.C.
NORONHA, F.B.
FONSECA, F.C.
Resumen
Ceria-based/Ni cermets were studied as the catalytic layer
deposited onto the standard yttria-stabilized zirconia/Ni anode for
direct ethanol solid oxide fuel cells. The influence of the dopant on
both Zr- and Nb-doped (10 mol%) ceria and pure ceria was
investigated on the properties of cermets with Ni ~15% volume
fraction. Electrolyte-supported fuel cells with ceria-based/Ni
catalytic layer were tested for ~100 hours under (dry) ethanol. Fuel
cells using the different ceria/Ni cermets showed excellent stability
on ethanol, irrespectively of the different properties of the ceramic
phase of the catalytic layer. Fuel cells results confirmed that the
studied ceria-based cermets are stable catalysts towards ethanol
steam reforming. Funda????o de Amparo ?? Pesquisa do Estado de S??o Paulo (FAPESP) FAPESP: 13/26961-7; 14/09087-4; 14/50279-4