Why silver deposition is so fast: Solving the enigma of metal deposition
Angewandte Chemie - International Edition, v. 52, n. 30, p. 7883-7885, 2013.
Pinto, Leandro M. C.
A perfect match: Silver deposition is one of the fastest electrochemical reactions, even though the Ag+ ion loses more than 5 eV solvation energy in the process. This phenomenon, an example of the enigma of metal deposition, was investigated by a combination of MD simulations, DFT, and specially developed theory. At the surface, the Ag+ ion experiences a strong interaction with the sp band of silver, which catalyzes the reaction. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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