| dc.contributor | Universidade Estadual Paulista (UNESP) | |
| dc.creator | De Carvalho, Sidney Jurado | |
| dc.creator | Caetano, Daniel Lucas Zago | |
| dc.date | 2014-05-27T11:29:47Z | |
| dc.date | 2016-10-25T18:50:12Z | |
| dc.date | 2014-05-27T11:29:47Z | |
| dc.date | 2016-10-25T18:50:12Z | |
| dc.date | 2013-06-28 | |
| dc.date.accessioned | 2017-04-06T02:28:14Z | |
| dc.date.available | 2017-04-06T02:28:14Z | |
| dc.identifier | Journal of Chemical Physics, v. 138, n. 24, 2013. | |
| dc.identifier | 0021-9606 | |
| dc.identifier | http://hdl.handle.net/11449/75725 | |
| dc.identifier | http://acervodigital.unesp.br/handle/11449/75725 | |
| dc.identifier | 10.1063/1.4811842 | |
| dc.identifier | WOS:000321148200057 | |
| dc.identifier | 2-s2.0-84879924684 | |
| dc.identifier | http://dx.doi.org/10.1063/1.4811842 | |
| dc.identifier.uri | http://repositorioslatinoamericanos.uchile.cl/handle/2250/896460 | |
| dc.description | In this work we investigate the adsorption of polyelectrolyte chains onto uniformly charged cylindrical macroions by means of the Metropolis Monte Carlo simulations and weighted histogram analysis method. Adopting a simplified model for macromolecules and treating the electrolytic solution in the Debye-Hückel level, conformational properties of the adsorbed chain, such as the radius of gyration and the thickness of the adsorbed layer, are provided as a function of ionic strength and macroion charge density. By analysis of the free energy profile as a function of the radius of gyration it was possible to identify first-order-like transitions between adsorbed and desorbed states and obtain a macroion charge density dependence of the critical ionic strength in good agreement with experiments. © 2013 AIP Publishing LLC. | |
| dc.language | eng | |
| dc.relation | Journal of Chemical Physics | |
| dc.rights | info:eu-repo/semantics/closedAccess | |
| dc.subject | Conformational properties | |
| dc.subject | Density dependence | |
| dc.subject | Electrolytic solution | |
| dc.subject | Macroion charges | |
| dc.subject | Metropolis Monte Carlo simulations | |
| dc.subject | Polyelectrolyte chain | |
| dc.subject | Radius of gyration | |
| dc.subject | Weighted histogram analysis method | |
| dc.subject | Ionic strength | |
| dc.subject | Monte Carlo methods | |
| dc.subject | Polyelectrolytes | |
| dc.subject | Adsorption | |
| dc.title | Adsorption of polyelectrolytes onto oppositely charged cylindrical macroions | |
| dc.type | Otro | |
