Otro
Effects of thermal treatment on phase transitions and on the mechanical relaxation in poly(vinylidene fluoride)
Registro en:
Proceedings - International Symposium on Electrets, p. 263-266.
10.1109/ISE.2002.1042993
WOS:000179971700063
2-s2.0-0036948954
0000-0001-8001-301X
Autor
Alves, Neri
Cardoso, C. X.
Job, A. E.
Giacometti, J. A.
Resumen
This work reports on the effects from thermal treatment in poly(vinylidene fluoride), PVDF, obtained with differential scanning calorimetry (DSC) and dynamic thermal analysis (DMA) measurements. It is shown that in successive DMA measurements performed with one sample the α relaxation peak almost disappears while the γ′ peak appears. The α relaxation peak, at ∼100°C in DMA measurements, is attributed to the preferential orientation of chains in the amorphous phase while the γ′ relaxation peak, at ∼50°C, is related to the thermal treatment to which the sample was submitted.