Otro
Insulator-to-metal transition driven by clustering of solitons in polyacetylene
Registro en:
Synthetic Metals, v. 85, n. 1-3, p. 1083-1084, 1997.
0379-6779
10.1016/S0379-6779(97)80157-9
WOS:A1997WX70800027
2-s2.0-0031069576
Autor
Lavarda, Francisco Carlos
Galvão, D. S.
Laks, B.
Resumen
It's believed that the simple Su-Schrieffer-Heeger Hamiltonian can not predict the insulator to metal transition of transpolyacetylene (t-PA). The soliton lattice configuration at a doping level y=6% still has a semiconductor gap. Disordered distributions of solitons close the gap, but the electronic states around the Fermi energy are localized. However, within the same framework, it is possible to show that a cluster of solitons can produce dramatic changes in the electronic structure, allowing an insulator-to-metal transition.