Otro
Metal carbonyls with zinciron bond: synthesis and vibrational spectra
Registro en:
Journal of Molecular Structure, v. 51, n. C, p. 9-16, 1979.
0022-2860
2-s2.0-49249152366
Autor
Mauro, A. E.
Hase, Y.
Sala, O.
Resumen
The compounds of the type LZnFe(CO)4 (L = dien, trien, tn, s-diMeen, Meen) not yet reported and (NH3)3ZnFe(CO)4, already known, were prepared and studied by IR and Raman spectroscopy. The data obtained suggest that LZnFe(CO)4, for L = (NH3)3, dien and trien are monomers with a bipyramidal trigonal configuration around the iron atom, while for L = tn, s-diMeen and Meen the complexes are probably polymers having a center of symmetry with iron atoms octahedrally co-ordinated. © 1979.