Otro
H-1-N-15 NMR studies of the complex bis(S-allyl-L-cysteinate)palladium(II)
Registro en:
Spectrochimica Acta Part A-molecular and Biomolecular Spectroscopy. Oxford: Pergamon-Elsevier B.V., v. 64, n. 2, p. 418-419, 2006.
1386-1425
10.1016/j.saa.2005.07.039
WOS:000238415900021
Autor
Corbi, P. P.
Massabni, Antonio Carlos
Resumen
H-1-N-15 2D NMR data for S-allyl-L-cysteine (deoxyalliin) and for bis(S-allyl-L-cysteinate)palladium(II) complex are presented in this manuscript. Large upfield N-15 NMR shift of the amine nitrogen in the spectrum of the complex when compared to the spectrum of the ligand shows clearly coordination of S-allyl-L-cysteine, in the anion form, to palladium(II) through the NH2 group. (c) 2005 Elsevier B.V. All rights reserved.