Artigo
Effects of the addition of ions barium on the structural and electrical properties of PZT ceramic
Registro en:
Materials Science Forum, v. 798-799, p. 199-204, 2014.
1662-9752
10.4028/www.scientific.net/MSF.798-799.199
3233942511496583
6134106111232960
5992362464264556
9128353103083394
Autor
Silva, Margarete Soares da
Teixeira, Guilhermina F.
Cavenago, Gustavo F.
Silva, Lucas L.
Dias, Rafael Gomes
Zaghete, Maria Aparecida [UNESP]
Cilense, Mario
Longo, Elson
Cavalheiro, Alberto Adriano
Resumen
Lead zirconate titanate, with Zr/Ti ratio of 53/47 was prepared by the polymeric precursor method. It was investigated the barium (II) modification at 0.0, 0.2, 0.4 and 0.6 mol% in substitution to the lead (II) cation in A site of perovskite structure. The powder samples were characterized by XRD and the diffraction patterns were used to Rietveld refinement. The percentages of tetragonal and rhombohedral phases and a systematic study of the effect of barium (II) on the morphology and the dielectric properties of PZT were carried out. The results showed that the tetragonal phase is favored and the ceramic density is improved with the barium (II) insertion. The Curie temperature (Tc) is increased besides the slight reduction of dielectric constant (Kc). Universidade Estadual Paulista Júlio de Mesquita Filho, Instituto de Química de Araraquara, Araraquara, Rua Professor Francisco Degni, Departamento de Química Analítica, Jardim Quitandinha, CEP 14800060, SP, Brasil