We investigate the relation between the four dimensional N = 2 SU(2) super Yang-Mills theory with four fundamental flavors and the quantum mechanics model with Treibich-Verdier potential described by the Heun equation in the elliptic form. We study the precise correspondence of quantities in the gauge theory and the quantum mechanics model. An iterative method is used to obtain the asymptotic expansion of the spectrum for the Schrodinger operator, we are able to fix the precise relation between the energy spectrum and the instanton partition function of the gauge theory. We also study asymptotic expansions for the spectrum which correspond to the strong coupling regions of the Seiberg-Witten theory.Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Univ Estadual Paulista, Inst Fis Teor, BR-01140070 Sao Paulo, BrazilUniv Estadual Paulista, Inst Fis Teor, BR-01140070 Sao Paulo, BrazilFAPESP: 11/21812-8