Supramolecular assemblies of cis-palladium complexes dominated by C-H center dot center dot center dot Cl interactions

Moro, A. C.; Watanabe, F. W.; Ananias, S. R.; Mauro, A. E.; Netto, A. V. G.; Lima, A. P. R.; Ferreira, J. G.; Santos, R. H. A.

dc.contributor	Universidade Estadual Paulista (UNESP)
dc.creator	Moro, A. C.
dc.creator	Watanabe, F. W.
dc.creator	Ananias, S. R.
dc.creator	Mauro, A. E.
dc.creator	Netto, A. V. G.
dc.creator	Lima, A. P. R.
dc.creator	Ferreira, J. G.
dc.creator	Santos, R. H. A.
dc.date	2014-05-20T15:20:25Z
dc.date	2016-10-25T17:53:32Z
dc.date	2014-05-20T15:20:25Z
dc.date	2016-10-25T17:53:32Z
dc.date	2006-05-01
dc.date.accessioned	2017-04-05T23:25:46Z
dc.date.available	2017-04-05T23:25:46Z
dc.identifier	Inorganic Chemistry Communications. Amsterdam: Elsevier B.V., v. 9, n. 5, p. 493-496, 2006.
dc.identifier	1387-7003
dc.identifier	http://hdl.handle.net/11449/31730
dc.identifier	http://acervodigital.unesp.br/handle/11449/31730
dc.identifier	10.1016/j.inoche.2006.02.012
dc.identifier	WOS:000237634800016
dc.identifier	http://dx.doi.org/10.1016/j.inoche.2006.02.012
dc.identifier.uri	http://repositorioslatinoamericanos.uchile.cl/handle/2250/876208
dc.description	Two cis-related palladium(II) complexes [PdCl(2)(PPh(3))(tu)] (1) and [PdCl(2)(tmen)] (2) {PPh(3) = triphenylphosphine, tu = thiourea, tmen = N,N,N,N-tetramethylethylenediamine} have been synthesized and characterized by elemental analysis, IR and NMR spectroscopies, and single crystal X-ray diffraction. In 1, N-H center dot center dot center dot Cl hydrogen bonds are responsible for the formation of a dimer which connects to an adjacent one through weak C-H center dot center dot center dot Cl interactions, yielding 1D tapes. The crystal packing of compound 2 consists of zigzag ribbons of [PdCl(2)(tmen)] self-assembled by C-H center dot center dot center dot Cl hydrogen bonds which also holds the chains together, giving rise to a 2D layered structure. (C) 2006 Elsevier B.V. All rights reserved.
dc.language	eng
dc.publisher	Elsevier B.V.
dc.relation	Inorganic Chemistry Communications
dc.rights	info:eu-repo/semantics/closedAccess
dc.subject	supramolecular chemistry
dc.subject	C-H center dot center dot center dot Cl hydrogen bonds
dc.subject	palladium(II)
dc.subject	self-assembly
dc.title	Supramolecular assemblies of cis-palladium complexes dominated by C-H center dot center dot center dot Cl interactions
dc.type	Otro

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Universidade Paulista Júlio de Mesquita Filho (Brasil)

Supramolecular assemblies of cis-palladium complexes dominated by C-H center dot center dot center dot Cl interactions

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