Artigo
Structural refinement, optical and electrical properties of [Ba1-x Sm-2x/3](Zr0.05Ti0.95)O-3 ceramics
Registro en:
Journal Of Materials Science-materials In Electronics. Dordrecht: Springer, v. 25, n. 8, p. 3427-3439, 2014.
0957-4522
10.1007/s10854-014-2035-7
WOS:000339331200026
Autor
Badapanda, T.
Sarangi, S.
Behera, B.
Anwar, S.
Sinha, T. P.
Ranjan, R.
Luz, G. E.
Longo, E. [UNESP]
Cavalcante, L. S.
Resumen
Samarium doped barium zirconate titanate ceramics with general formula [Ba1-x Sm-2x/3](Zr0.05Ti0.95)O-3 [x = 0, 0.01, 0.02, and 0.03] were prepared by high energy ball milling method. X-ray diffraction patterns and micro-Raman spectroscopy confirmed that these ceramics have a single phase with a tetragonal structure. Rietveld refinement data were employed to model [BaO12], [SmO12], [ZrO6], and [TiO6] clusters in the lattice. Scanning electron microscopy shows a reduction in average grain size with the increase of Sm3+ ions into lattice. Temperature-dependent dielectric studies indicate a ferroelectric phase transition and the transition temperature decreases with an increase in Sm3+ ion content. The nature of the transition was investigated by the Curie-Weiss law and it is observed that the diffusivity increases with Sm3+ ion content. The ferroelectric hysteresis loop illustrates that the remnant polarization and coercive field increase with an increase in Sm3+ ions content. Optical properties of the ceramics were studied using ultraviolet-visible diffuse reflectance spectroscopy. Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) CV Raman Coll Engn, Dept Phys, Bhubaneswar 752054, Odisha, India Sambalpur Univ, Sch Phys, Jyoti Vihar Sambalpur 768019, Odisha, India Inst Minerals & Mat Technol, Bhubaneswar 751013, Odisha, India Bose Inst, Dept Phys, Kolkata 700009, W Bengal, India Indian Inst Sci, Dept Mat Engn, Bangalore 560012, Karnataka, India Univ Estadual Piaui, CCN DQ GERATEC, BR-64002150 Teresina, PI, Brazil Univ Estadual Paulista CDMF, BR-14801907 Araraquara, SP, Brazil Univ Estadual Paulista CDMF, BR-14801907 Araraquara, SP, Brazil CNPq: 304531/2013-8 CNPq: 479644/2012-8 CNPq: 555684/2009-1