dc.contributorUniversidade Estadual Paulista (UNESP)
dc.creatorBruno, J. C.
dc.creatorBoni, T. C.
dc.creatorCavalheiro, A. A.
dc.creatorZaghete, M. A.
dc.date2014-05-20T13:53:39Z
dc.date2016-10-25T17:04:06Z
dc.date2014-05-20T13:53:39Z
dc.date2016-10-25T17:04:06Z
dc.date2008-02-05
dc.date.accessioned2017-04-05T21:09:09Z
dc.date.available2017-04-05T21:09:09Z
dc.identifierMaterials Research Bulletin. Oxford: Pergamon-Elsevier B.V. Ltd, v. 43, n. 2, p. 297-304, 2008.
dc.identifier0025-5408
dc.identifierhttp://hdl.handle.net/11449/19157
dc.identifierhttp://acervodigital.unesp.br/handle/11449/19157
dc.identifier10.1016/j.materresbull.2007.03.010
dc.identifierWOS:000252579800013
dc.identifierhttp://dx.doi.org/10.1016/j.materresbull.2007.03.010
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/865101
dc.descriptionThe present work reports the effects caused by barium on phase formation, morphology and sintering of lead magnesium niobate-lead titanate (PMN-50PT). Ab initio study of 0.5PbMg(1/3)Nb(2/3)O(3)-0.5Ba(x)Pb((1-x))TiO(3) ceramic powders, with x = 0, 0.20, and 0.40 was proposed, considering that the partial substitution of lead by barium can reestablish the equilibrium of monoclinic-tetragonal phases in the system. It was verified that even for 40 mol% of barium, it was possible to obtain pyrochlore-free PMN-PT powders. The increase of the lattice parameters of PMN-PT doped-powders confirmed dopant incorporation into the perovskite phase. The presence of barium improved the reactivity of the powders, with an average particle size of 120 nm for 40 mol% of barium against 167 mn for the pure sample. Although high barium content (40 mol%) was deleterious for a dense ceramic, contents up to 20 mol% allowed 95% density when sintered at 1100 degrees C for 4 h. (c) 2007 Elsevier Ltd. All rights reserved.
dc.languageeng
dc.publisherPergamon-Elsevier B.V. Ltd
dc.relationMaterials Research Bulletin
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectceramics
dc.subjectX-ray diffraction
dc.subjectphase equilibria
dc.titleStructural characterization of 0.5PbMg(1/3)Nb(2/3)O(3)-0.5Ba(x)Pb((1-x))TiO(3) powders
dc.typeOtro


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