N-heptane oxidation mediated by the coordination compound [Mn(C16H14N2O2)AcO]
Oxidación de n-heptano mediada por el compuesto de coordinación [Mn(C16H14N2O2)AcO]
| dc.creator | Viasus, Camilo Javier | |
| dc.creator | Riveros, Raúl Alberto | |
| dc.creator | Alzate, John Alexander | |
| dc.creator | Burgos, Ana Esperanza | |
| dc.date | 2011-12-31 | |
| dc.date.accessioned | 2023-08-28T15:13:08Z | |
| dc.date.available | 2023-08-28T15:13:08Z | |
| dc.identifier | https://revistas.udca.edu.co/index.php/ruadc/article/view/791 | |
| dc.identifier.uri | https://repositorioslatinoamericanos.uchile.cl/handle/2250/8442780 | |
| dc.description | The amounts of hydrocarbons that are produced today by the oil industry continue to increase causing great environmental pollution. The reaction present here is an alternative to waste hydrocarbons recovery. In this work it present the n-heptane oxidation mediated by the coordination compound [Mn(C16H14N2O2)AcO]. The most significant reaction products were alcohol (n-buthanol) and seven carbons ketones (mainly 2-heptanone, 3-heptanone and 4-heptanone). The n-hepthane oxidation is favored toward the formation to n-butanol in aqueous medium and ketone formation in solvent without water. The oxidation products were identified by GC-MS | en-US |
| dc.description | La cantidad de hidrocarburos que son producidos en la actualidad por la industria petrolera continúan en incremento, causando gran contaminación ambiental. La reacción lograda en este trabajo es una alternativa a la recuperación de residuos hidrocarbonados industriales. En este trabajo, se presenta la oxidación de n-heptano, mediada por el compuesto de coordinación [Mn(C16H14N2O2)AcO]. Los productos más significativos de la reacción fueron alcoholes (n-butanol) y cetonas de siete carbonos (2-heptanona, 3-heptanona y 4-heptanona, principalmente). La oxidación de n-heptano se ve favorecida hacia la formación de n-butanol, en medio acuoso y, a la formación de cetonas, en medio no acuoso. Los productos de la oxidación fueron identificados mediante CG-EM. | es-ES |
| dc.format | application/pdf | |
| dc.format | text/html | |
| dc.language | spa | |
| dc.publisher | Universidad de Ciencias Aplicadas y Ambientales U.D.C.A | es-ES |
| dc.relation | https://revistas.udca.edu.co/index.php/ruadc/article/view/791/869 | |
| dc.relation | https://revistas.udca.edu.co/index.php/ruadc/article/view/791/870 | |
| dc.relation | /*ref*/BOAEN, N.K.; HILLMYER, M.A. 2003. Selective and mild oxyfunctionalization of model polyolefins. Macromolecules, 36(19):7027-7034. | |
| dc.relation | /*ref*/COSTAS, M. 2011. Selective C-H oxidation catalyzed by metalloporphyrins. Chem Coord. Rev. In press. Disponible desde Internet en: http://www.sciencedirect. com/science/article/pii/S0010854511001780(con acceso 06/07/11). | |
| dc.relation | /*ref*/CRABTREE, R.H. 2004. Organometallic alkane CH activation. J. Organometallic Chem. 689:4083-4091. | |
| dc.relation | /*ref*/DYKER, G. 2005. Handbook of C-H transformation, Wiley-VCH, Weinheim: p.11-24 y 497-524. | |
| dc.relation | /*ref*/JACOBSEN, E.N.; KAKIUCHI, F.; KONSLER, R.G.; LARROW, J.F.; TOKUNAGA, M. 1997. Enantioselective catalytic ring opening of epoxides with carboxylic acids. Tetrahedron Letters. 38(5):773-776. | |
| dc.relation | /*ref*/JACOBSEN, E.N. 1995. Transition metal-catalyzed oxidations: asymmetric epoxidation. En: Edward, W.A.; Stone, F.G.A; Geoffrey, W. (eds). Comprehensive organometallic chemistry II. Oxford, Elsevier.p. 1097- 1135. | |
| dc.relation | /*ref*/JACOBSEN, E.N.; DENG, L.; FURUKAWA, Y.; MARTÍNEZ, L.E. 1994. Enantioselective catalytic epoxidation of cinnamate esters. Tetrahedron, 50(15):4323-4334. | |
| dc.relation | /*ref*/MEHDI, H.; MAJID, M.; IRAN, S.; VALIOLLAH, M.; SHAHRAM, T.; IRAJ, M.; HADI, K. 2009. Ru(salophen)Cl supported on polystyrene-bound imidazole: an efficient and robust heterogeneous catalyst for epoxidation of alkenes with sodium periodate. Applied Catalysis A: General. 370: 66-71. | |
| dc.relation | /*ref*/OLAH, G.A.; MOLNÁR, Á. 2003. Hydrocarbon chemistry, 2nd ed., Wiley, New York. P.427-529. | |
| dc.relation | /*ref*/PALUCKI, M.; HANSON, P.; JACOBSEN, E.N. 1992. Asymmetric oxidation of sulfides with H2O2 catalyzed by Mn(III)(Salen) complexes. Tetrahedron Letters. 33(47):7111-7114. | |
| dc.relation | /*ref*/PALUCKI, M.; McCORMICK, G.J.; JACOBSEN, E.N. 1995. Low temperature asymmetric epoxidation of unfunctionalized olefins catalyzed by Mn(III)(salen) complexes. Tetrahedron Letters. 36(31):5457-5460. | |
| dc.relation | /*ref*/PECORARO, V.L.; BUTLER, W.M. 1986. Structure of N,N'-ethylenebis(salicylideneiminato)manganese(III) chloride acetonitrile solvate. Acta Crystallography. C42:1151-1154. | |
| dc.relation | /*ref*/SHAHRAM, T.; MOGHADAM, M.; MIRKHANI, V.; MOHAMMADPOOR-BALTORK, I.; SAEEDI, M.S. 2010. Efficient epoxidation of alkenes with sodium periodate catalyzed by reusable manganese(III) salophen supported on multi-wall carbon nanotubes. Applied Catalysis A: General. 381:233-241. | |
| dc.relation | /*ref*/SHILOV, A.E.; SHUL`PIN, G.B. 2000. Activation and catalytic reactions of saturated hydrocarbons in the presence of metal complexes. Springer-Verlag, Boston. p.8-19 y 127-187. | |
| dc.relation | /*ref*/SUN, C-L.; LI, B.J.; SHI. Z-J. 2011. Direct C-H Transformation via Iron Catalysis. Chemical. Review. 111(3): 1293-314. | |
| dc.relation | /*ref*/VALIOLLAH, M.; MAJID, M.; SHAHRAM, T.; BAHRAM, B. 2006. Silica-bound imidazole as a heterogeneous axial ligand for Mn(salophen)Cl: efficient, recoverable and recyclable catalyst for epoxidation of alkenes and hydroxylation of alkanes with sodium periodate. Applied Catalysis A: General, 313:122-129. | |
| dc.source | Revista U.D.C.A Actualidad & Divulgación Científica; Vol. 14 No. 2 (2011): Revista U.D.C.A Actualidad & Divulgación Científica. Julio-Diciembre; 141-149 | en-US |
| dc.source | Revista U.D.C.A Actualidad & Divulgación Científica; Vol. 14 Núm. 2 (2011): Revista U.D.C.A Actualidad & Divulgación Científica. Julio-Diciembre; 141-149 | es-ES |
| dc.source | Revista U.D.C.A Actualidad & Divulgación Científica; v. 14 n. 2 (2011): Revista U.D.C.A Actualidad & Divulgación Científica. Julio-Diciembre; 141-149 | pt-BR |
| dc.source | 2619-2551 | |
| dc.source | 0123-4226 | |
| dc.source | 10.31910/rudca.v14.n2.2011 | |
| dc.subject | Oxidación | es-ES |
| dc.subject | Hidrocarburos | es-ES |
| dc.subject | [Mn(salen)AcO] | es-ES |
| dc.subject | Recuperación de residuos | es-ES |
| dc.subject | Oxidation | en-US |
| dc.subject | Hydrocarbons | en-US |
| dc.subject | [Mn(salen)AcO] | en-US |
| dc.subject | Waste recovery | en-US |
| dc.title | N-heptane oxidation mediated by the coordination compound [Mn(C16H14N2O2)AcO] | en-US |
| dc.title | Oxidación de n-heptano mediada por el compuesto de coordinación [Mn(C16H14N2O2)AcO] | es-ES |
| dc.type | info:eu-repo/semantics/article | |
| dc.type | info:eu-repo/semantics/publishedVersion |