Articulo
Dicyclohexylphosphino cyrhetrene: synthesis, characterization and catalytic evaluation toward suzuki-miyaura cross-coupling reaction of aryl bromides and chlorides
Inorganic Chemistry Communications
Registro en:
1150601
1150601
Autor
Sierra, Diego
Brito, German
Fuentealba, Mauricio
Hugo Klahn, A
Institución
Resumen
Reaction of cyrhetrene ((eta(5)-C5H5)Re(CO)(3)) with n-butyllithium (1.0 equiv, -78 degrees C) and then CIPCy2 (Cy = cyclohexyl) gives the new cyrhetrenyl-phosphino ligand (eta(5)-C5H4PCy2)Re(CO)(3) which was isolated as a pure sample in 86% yield and ch Regular FONDECYT FONDECYT