Critical temperatures of real fluids from the extended law of corresponding states

dc.creatorGonzález-Calderón Alfredo
dc.creatorJORGE ADRIAN PERERA BURGOS
dc.creatorDaniel Porfirio Luis Jiménez
dc.date2019
dc.date.accessioned2023-07-21T19:18:58Z
dc.date.available2023-07-21T19:18:58Z
dc.identifierhttp://cicy.repositorioinstitucional.mx/jspui/handle/1003/1700
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/7737262
dc.descriptionThe extended law of corresponding states was proposed based on the patterns observed in the second virial coefficient for potential models of variable range. In this work, we propose the use of this law, together with a generalized Lennard-Jones (or approximate nonconformal, ANC) potential, to predict the critical temperatures of real fluids. To this end, we first observe that the temperatures obtained from the scaling law are in agreement with those obtained from molecular simulations of ANC fluids. For short ranges, however, validation is performed by mapping the ANC fluid to the square well fluid because no simulation data have been reported for the former fluid for these ranges. Overall, the analysis shows the validity of the scaling law and the ANC potential for predicting critical temperatures for any range. With this in mind, the well depths of the effective binary potentials of atoms and molecules are rescaled to apply a correction for the three-body nonadditive interaction in order to determine the critical temperatures of fluids.
dc.formatapplication/pdf
dc.languageeng
dc.relationinfo:eu-repo/semantics/datasetDOI/10.1063/1.5123613
dc.relationcitation:González-Calderón, A., Perera-Burgos, J. A., & Luis, D. P. (2019). Critical temperatures of real fluids from the extended law of corresponding states. AIP Advances, 9(11), 115217.
dc.rightsinfo:eu-repo/semantics/openAccess
dc.rightshttp://creativecommons.org/licenses/by-nc-nd/4.0
dc.sourceAIP Advances, 9(11), 115217, 2019
dc.subjectinfo:eu-repo/classification/Autores/NANOSCIENCE & NANOTECHNOLOGY
dc.subjectinfo:eu-repo/classification/Autores/MATERIALS SCIENCE
dc.subjectinfo:eu-repo/classification/Autores/MULTIDISCIPLINARY
dc.subjectinfo:eu-repo/classification/Autores/PHYSICS
dc.subjectinfo:eu-repo/classification/Autores/APPLIED
dc.subjectinfo:eu-repo/classification/cti/7
dc.subjectinfo:eu-repo/classification/cti/33
dc.subjectinfo:eu-repo/classification/cti/3312
dc.subjectinfo:eu-repo/classification/cti/331208
dc.subjectinfo:eu-repo/classification/cti/331208
dc.titleCritical temperatures of real fluids from the extended law of corresponding states
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion


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