Articulo
Influence of the essential features of the potential energy surface on the temperature dependence of the H+CH₃→CH₄ reaction
Registro en:
issn:0133-1736
issn:1588-2837
Autor
Cobos, Carlos Jorge
Institución
Resumen
Microcanonical statistical adiabatic channel model calculations show that the temperature dependence of the limiting high pressure rate coefficients of the title reaction becomes less positive (or more negative) when the attractiveness of the radial or the attenuation of anisotropic parts of the potential energy surface increases. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas