Articulo
Crystal and molecular structure determination, TGA-DTA, and infrared and Raman spectra of rubidium nitroprusside, Rb<SUB>2</SUB>[Fe(CN)<SUB>5</SUB>NO]
Registro en:
issn:1074-1542
issn:1572-8854
issn:0308-4086
issn:0277-8068
Autor
Soria, Delia Beatriz
Amalvy, Javier Ignacio
Piro, Oscar Enrique
Castellano, Eduardo Ernesto
Aymonino, Pedro José
Institución
Resumen
The title compound, Rb2[Fe(CN)5NO], crystallizes in the space group P212121, witha=5.687(1),b=15.956(2),c=12.645(3) A, andZ=4. Anions are in equivalent C1 sites (one per asymmetric unit) and are slightly distorted octahedra (C4v ideal symmetry). TGA and DTA curves and vibrational (infrared and Raman) spectra of Rb2[Fe(CN)5NO] were obtained. Results are interpreted in view of the crystal structure of the compound and the behavior of related substances. Facultad de Ciencias Exactas Centro de Investigación y Desarrollo en Tecnología de Pinturas