Articulo
Structural, Spectroscopic, and Thermal Behaviour of Bis-(thiosaccharinate)- aqua-cadmium(II)
Registro en:
issn:0026-9247
issn:1434-4475
issn:0343-7329
Autor
Tarulli, Susana H.
Quinzani, Oscar V.
Piro, Oscar Enrique
Baran, Enrique José
Castellano, Eduardo E.
Institución
Resumen
The crystal structure of the title complex, [Cd(tsac)2(H2O)], has been determined by single crystal X-ray diffraction methods. It crystallizes in the monoclinic space group C2/c (a = 12.236(3), b = 8.919(3), c = 16.655(3) A, β = 96.18(2)°, Z = 4). The molecular structure was solved from 1705 independent reflections with I > σ(I) and refined to R1 = 0.0489. Infrared and Raman spectra of the complex were recorded and are briefly discussed. Its thermal behaviour was investigated by thermogravimetry and differential thermal analysis. Instituto de Física La Plata Centro de Química Inorgánica