Study of Pt and Rh based supported catalysts modified with tetrabutyltin for the selective hydrogenation of 4-methoxyacetophenone

Vetere, Virginia; Casella, Mónica Laura; Tálas, Emilia; Gőbölös, Sándor; Ferretti, Osmar

Articulo

Registro en:

http://sedici.unlp.edu.ar/handle/10915/139043

issn:0133-1736

issn:1588-2837

https://repositorioslatinoamericanos.uchile.cl/handle/2250/7470748

Autor

Vetere, Virginia

Casella, Mónica Laura

Tálas, Emilia

Gőbölös, Sándor

Ferretti, Osmar

Institución

Universidad Nacional de La Plata (Argentina)

Resumen

Catalysts based on Pt and Rh modified with Sn(C4H9)4 were studied in the hydrogenation of 4-methoxyacetophenone. The selectivity to 1-(4-methoxyphenyl)ethanol was close to 100% at Sn/(Pt,Rh) = 1.0, however the catalytic activity decreased drastically. With respect to the balance between activity and selectivity the catalyst PtSnOM (Sn/Pt=0.4) showed the best performance.

Centro de Investigación y Desarrollo en Ciencias Aplicadas

Materias

Química

Ciencias Exactas

4-Methoxyacetophenone hydrogenation

tin modified Pt and Rh catalysts

organometallic chemistry

Mostrar el registro completo del ítem