Articulo
Allowed permutation symmetry in atomic and molecular wavefunctions: simple examples
Registro en:
issn:0953-4075
issn:1361-6455
Autor
Fernández, Francisco Marcelo
Institución
Resumen
It is well known that the allowed wavefunctions for an N-electron system should be antisymmetric with respect to the permutation of any pair of electron labels. On the other hand, the Hamiltonian for such system is invariant under any permutation of electron labels and, consequently, its eigenfunctions are basis for the irreducible representations of the symmetric group S<sub>N</sub>.Here, we investigate which symmetry species of the S<sub>N</sub> group are compatible with the antisymmetry principle. We illustrate the conclusions by means of simple N-particle one-dimensional models with harmonic interactions. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas