| dc.creator | Parente, Juliana Elena | |
| dc.creator | Williams, Patricia Ana María | |
| dc.creator | Ferrer, Evelina Gloria | |
| dc.date | 2020 | |
| dc.date | 2021-08-25T15:02:31Z | |
| dc.date.accessioned | 2023-07-15T02:50:10Z | |
| dc.date.available | 2023-07-15T02:50:10Z | |
| dc.identifier | http://sedici.unlp.edu.ar/handle/10915/123369 | |
| dc.identifier | issn:1559-0720 | |
| dc.identifier | issn:0163-4984 | |
| dc.identifier.uri | https://repositorioslatinoamericanos.uchile.cl/handle/2250/7463454 | |
| dc.description | Peroxidovanadium(V) and oxidovanadium(IV) compounds have been tested as peroxidase-similar compounds. Their catalytic performance was tested on phenol red and pyrogallol substrates. Bromination kinetic studies revealed Michaelis-Menten behavior with respect to phenol red for both complexes. Catalytic efficiency is ~ 104 M−1 min−1. Both vanadium complexes showed the capacity to oxidize pyrogallol, but only the oxidovanadium (IV) complex follows Michaelis-Menten kinetics with respect to this substrate (Km = 1.05 × 10-3 M). Peroxidovanadium(V) complex displayed a more complex mechanism, and further studies became necessary to elucidate it. The structure-activity relationship was also assessed. | |
| dc.description | Centro de Química Inorgánica | |
| dc.format | application/pdf | |
| dc.format | 725-731 | |
| dc.language | en | |
| dc.rights | http://creativecommons.org/licenses/by-nc-sa/4.0/ | |
| dc.rights | Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) | |
| dc.subject | Química | |
| dc.subject | Biocatalyst models | |
| dc.subject | Peroxidase-similar activity | |
| dc.subject | Phenol red | |
| dc.subject | Pyrogallol | |
| dc.subject | Vanadium complexes | |
| dc.title | Vanadium Compounds as Biocatalyst Models | |
| dc.type | Articulo | |
| dc.type | Articulo | |
