Articulo
Specific Heat Anomaly in a Supercooled Liquid with Amorphous Boundary Conditions
Registro en:
issn:0031-9007
Autor
Mártin, Daniel A.
Cavagna, Andrea
Grigera, Tomás Sebastián
Institución
Resumen
We study the specific heat of a model supercooled liquid confined in a spherical cavity with amorphous boundary conditions. We find the equilibrium specific heat has a cavity-size-dependent peak as a function of temperature. The cavity allows us to perform a finite-size scaling (FSS) analysis, which indicates that the peak persists at a finite temperature in the thermodynamic limit. We attempt to collapse the data onto a FSS curve according to different theoretical scenarios, obtaining reasonable results in two cases: a "not-so-simple" liquid with nonstandard values of the exponents α and ν, and random first-order theory, with two different length scales. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas Facultad de Ingeniería Facultad de Ciencias Exactas