dc.creatorMorales-Verdejo, César [Univ Mayor, Fac Ciencias, Ctr Nanotecnol Aplicada]
dc.creatorCamarada, María Belén [Univ Mayor, Fac Ciencias, Ctr Nanotecnol Aplicada, Santiago, Chile]
dc.creatorMorales, Veronica
dc.creatorCanete, Alvaro
dc.creatorMartínez, Ivan
dc.creatorManríquez, Juan Manuel
dc.creatorChávez, Ivonne
dc.date.accessioned2020-04-08T14:11:55Z
dc.date.accessioned2020-04-13T18:12:49Z
dc.date.accessioned2022-10-18T18:41:01Z
dc.date.available2020-04-08T14:11:55Z
dc.date.available2020-04-13T18:12:49Z
dc.date.available2022-10-18T18:41:01Z
dc.date.created2020-04-08T14:11:55Z
dc.date.created2020-04-13T18:12:49Z
dc.date.issued2018
dc.identifierMorales-Verdejo, C., Camarada, M. B., Morales, V., Cañete, Á., Martínez, I., Manriquez, J. M., & Chávez, I. (2018). PRELIMINARY RESULTS OF THE REACTION OF CYCLOTRIMERIZATION OF PHENYLACETYLENE [2+ 2+ 2] CATALYZED BY [(Cp*) Co (Indene)] COMPLEX. Journal of the Chilean Chemical Society, 63(1), 3898-3901.
dc.identifier0717-9707
dc.identifierhttps://doi.org/10.4067/s0717-97072018000103898
dc.identifierhttp://repositorio.umayor.cl/xmlui/handle/sibum/6242
dc.identifierDOI: 10.4067/s0717-97072018000103898
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/4454085
dc.description.abstractThis work describes the catalytic study of [(Cp*)Co(Ind)] (with Cp*- pentamethylcyclopentadienyl, Ind = Indenyl, (C9H7)) complex in cyclotrimerization of phenylacetylene. From the cylcotrimerization reaction was possible to obtain products such as substituted pyridines 2-methyl-3,5-diphenylpyridine (3), 2-methyl-4,6-diphenylpyridine (4) and the compound 1,2,4-triphenylbenzene (5) using acetonitrile as solvent. On the other hand, using toluene as solvent under the same working conditions, the product of reaction was 1,3,5-triphenylbenzene (1). Furthermore, by varying the working conditions, the reaction is 90% selective towards the formation of pyridines. In addition, has been appreciated the formation of another product 1,4-diphenilbuta-1.3-diyne (2), which was isolated and characterized by means NMR and GC-Mass spectrometry.
dc.languageen
dc.publisherSOC CHILENA QUIMICA
dc.rightsAttribution-NonCommercial-NoDerivs 3.0 Chile
dc.sourceJ. Chil. Chem. Soc., MAR 2018. 63(1): p. 3898-3901
dc.subjectChemistry, Multidisciplinary
dc.titlePRELIMINARY RESULTS OF THE REACTION OF CYCLOTRIMERIZATION OF PHENYLACETYLENE [2+2+2] CATALYZED BY [(Cp*)Co(Indene)] COMPLEX
dc.typeArtículos de revistas


Este ítem pertenece a la siguiente institución