dc.creator | Morales-Verdejo, César [Univ Mayor, Fac Ciencias, Ctr Nanotecnol Aplicada] | |
dc.creator | Camarada, María Belén [Univ Mayor, Fac Ciencias, Ctr Nanotecnol Aplicada, Santiago, Chile] | |
dc.creator | Morales, Veronica | |
dc.creator | Canete, Alvaro | |
dc.creator | Martínez, Ivan | |
dc.creator | Manríquez, Juan Manuel | |
dc.creator | Chávez, Ivonne | |
dc.date.accessioned | 2020-04-08T14:11:55Z | |
dc.date.accessioned | 2020-04-13T18:12:49Z | |
dc.date.accessioned | 2022-10-18T18:41:01Z | |
dc.date.available | 2020-04-08T14:11:55Z | |
dc.date.available | 2020-04-13T18:12:49Z | |
dc.date.available | 2022-10-18T18:41:01Z | |
dc.date.created | 2020-04-08T14:11:55Z | |
dc.date.created | 2020-04-13T18:12:49Z | |
dc.date.issued | 2018 | |
dc.identifier | Morales-Verdejo, C., Camarada, M. B., Morales, V., Cañete, Á., Martínez, I., Manriquez, J. M., & Chávez, I. (2018). PRELIMINARY RESULTS OF THE REACTION OF CYCLOTRIMERIZATION OF PHENYLACETYLENE [2+ 2+ 2] CATALYZED BY [(Cp*) Co (Indene)] COMPLEX. Journal of the Chilean Chemical Society, 63(1), 3898-3901. | |
dc.identifier | 0717-9707 | |
dc.identifier | https://doi.org/10.4067/s0717-97072018000103898 | |
dc.identifier | http://repositorio.umayor.cl/xmlui/handle/sibum/6242 | |
dc.identifier | DOI: 10.4067/s0717-97072018000103898 | |
dc.identifier.uri | https://repositorioslatinoamericanos.uchile.cl/handle/2250/4454085 | |
dc.description.abstract | This work describes the catalytic study of [(Cp*)Co(Ind)] (with Cp*- pentamethylcyclopentadienyl, Ind = Indenyl, (C9H7)) complex in cyclotrimerization of phenylacetylene. From the cylcotrimerization reaction was possible to obtain products such as substituted pyridines 2-methyl-3,5-diphenylpyridine (3), 2-methyl-4,6-diphenylpyridine (4) and the compound 1,2,4-triphenylbenzene (5) using acetonitrile as solvent. On the other hand, using toluene as solvent under the same working conditions, the product of reaction was 1,3,5-triphenylbenzene (1). Furthermore, by varying the working conditions, the reaction is 90% selective towards the formation of pyridines. In addition, has been appreciated the formation of another product 1,4-diphenilbuta-1.3-diyne (2), which was isolated and characterized by means NMR and GC-Mass spectrometry. | |
dc.language | en | |
dc.publisher | SOC CHILENA QUIMICA | |
dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Chile | |
dc.source | J. Chil. Chem. Soc., MAR 2018. 63(1): p. 3898-3901 | |
dc.subject | Chemistry, Multidisciplinary | |
dc.title | PRELIMINARY RESULTS OF THE REACTION OF CYCLOTRIMERIZATION OF PHENYLACETYLENE [2+2+2] CATALYZED BY [(Cp*)Co(Indene)] COMPLEX | |
dc.type | Artículos de revistas | |