dc.creator | Franco, Diego Gaspar | |
dc.creator | Fuertes, Valeria Cintia | |
dc.creator | Blanco, Marìa Cecilia | |
dc.creator | Fernández Díaz, M. T. | |
dc.creator | Sanchez, Rodolfo Daniel | |
dc.creator | Carbonio, Raul Ernesto | |
dc.date.accessioned | 2019-01-24T20:49:21Z | |
dc.date.accessioned | 2022-10-15T14:54:52Z | |
dc.date.available | 2019-01-24T20:49:21Z | |
dc.date.available | 2022-10-15T14:54:52Z | |
dc.date.created | 2019-01-24T20:49:21Z | |
dc.date.issued | 2012-10 | |
dc.identifier | Franco, Diego Gaspar; Fuertes, Valeria Cintia; Blanco, Marìa Cecilia; Fernández Díaz, M. T.; Sanchez, Rodolfo Daniel; et al.; Synthesis, structure and magnetic properties of La 3Co 2SbO 9: A double perovskite with competing antiferromagnetic and ferromagnetic interactions; Academic Press Inc Elsevier Science; Journal of Solid State Chemistry; 194; 10-2012; 385-391 | |
dc.identifier | 0022-4596 | |
dc.identifier | http://hdl.handle.net/11336/68566 | |
dc.identifier | CONICET Digital | |
dc.identifier | CONICET | |
dc.identifier.uri | https://repositorioslatinoamericanos.uchile.cl/handle/2250/4399265 | |
dc.description.abstract | The synthesis, structural characterization, and magnetic properties of La 3Co 2SbO 9 double perovskite are reported. The crystal structure has been refined by X-ray and neutron powder diffraction data in the monoclinic space group P2 1/n. Co 2 and Sb 5 have the maximum order allowed for the La 3Co 2SbO 9 stoichiometry. Rietveld refinements of powder neutron diffraction data show that at room temperature the cell parameters are a=5.6274(2) Å, b=5.6842(2) Å, c=7.9748(2) Å and β=89.999(3)°. Magnetization measurements indicate the presence of ferromagnetic correlations with T C=55 K attributed to the exchange interactions for non-linear Co 2-O-Sb 5-O-Co 2 paths. The effective magnetic moment obtained experimentally is μ exp=4.38 μ B (per mol Co 2), between the theoretical one for spin only (3.87 μ B) and spin-orbit value (6.63 μ B), indicating partially unquenched contribution. The low magnetization value at high magnetic field and low temperature (1 μ B/f.u., 5 T and 5 K) and the difference between ZFC and FC magnetization curves (at 5 kOe) indicate that the ferromagnetism do not reach a long range order and that the material has an important magnetic frustration. | |
dc.language | eng | |
dc.publisher | Academic Press Inc Elsevier Science | |
dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.jssc.2012.05.045 | |
dc.relation | info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0022459612003738 | |
dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | |
dc.rights | info:eu-repo/semantics/restrictedAccess | |
dc.subject | DOUBLE PEROVSKITE | |
dc.subject | FERROMAGNETIC | |
dc.subject | LA 3CO 2SBO 9 | |
dc.subject | MAGNETIC FRUSTRATION | |
dc.subject | POWDER NEUTRON DIFFRACTION | |
dc.subject | RIETVELD REFINEMENT | |
dc.title | Synthesis, structure and magnetic properties of La 3Co 2SbO 9: A double perovskite with competing antiferromagnetic and ferromagnetic interactions | |
dc.type | info:eu-repo/semantics/article | |
dc.type | info:ar-repo/semantics/artículo | |
dc.type | info:eu-repo/semantics/publishedVersion | |