4'-[2-(2-Ethoxy-ethoxy)eth-oxy]-bi-phenyl-4-carboxylic acid: Correlation between its crystalline and smectic phases

dc.creatorMontani, Rosana Silvia
dc.creatorGaray, Raúl Oscar
dc.creatorCukiernik, Fabio Daniel
dc.creatorGarland, Maria T.
dc.creatorBaggio, Ricardo Fortunato
dc.date.accessioned2018-12-04T15:04:29Z
dc.date.accessioned2022-10-15T13:50:24Z
dc.date.available2018-12-04T15:04:29Z
dc.date.available2022-10-15T13:50:24Z
dc.date.created2018-12-04T15:04:29Z
dc.date.issued2009-12
dc.identifierMontani, Rosana Silvia; Garay, Raúl Oscar; Cukiernik, Fabio Daniel; Garland, Maria T.; Baggio, Ricardo Fortunato; 4'-[2-(2-Ethoxy-ethoxy)eth-oxy]-bi-phenyl-4-carboxylic acid: Correlation between its crystalline and smectic phases; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C-Crystal Structure Communications; 65; 3; 12-2009; 81-84
dc.identifier0108-2701
dc.identifierhttp://hdl.handle.net/11336/65716
dc.identifierCONICET Digital
dc.identifierCONICET
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/4393390
dc.description.abstractThe crystal structure of the dimeric title compound, C19H 22O5H, is dominated by a head-to-head hydrogen-bonding inter-action between centrosymmetrically related carboxyl groups in each monomer. The result is a dimeric axis of unusual length (ca 34 Å), but still shorter than what could be expected for a fully extended chain, owing to two turning points in the oligo-eth-oxy ends. This allows for an explanation of the structure of the smectic mesophase exhibited by this compound and at the same time fully validates former geometric estimations based on PM3 calculations. © 2009 International Union of Crystallography.
dc.languageeng
dc.publisherWiley Blackwell Publishing, Inc
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/https://dx.doi.org/10.1107/S0108270109001991
dc.relationinfo:eu-repo/semantics/altIdentifier/url/http://scripts.iucr.org/cgi-bin/paper?S0108270109001991
dc.relationinfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/full/10.1107/S0108270109001991?sentby=iucr
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.rightsinfo:eu-repo/semantics/restrictedAccess
dc.subjectstructure
dc.subjectmesophase
dc.subjectdimeric
dc.subjecthydrogen-bonding
dc.title4'-[2-(2-Ethoxy-ethoxy)eth-oxy]-bi-phenyl-4-carboxylic acid: Correlation between its crystalline and smectic phases
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:ar-repo/semantics/artículo
dc.typeinfo:eu-repo/semantics/publishedVersion


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