SiF4 IR Photodissociation: Gas phase reactions of SiF3 with CH4

dc.creatorAlcaraz, A. N.
dc.creatorCodnia, Jorge
dc.creatorAzcárate, María Laura
dc.date.accessioned2019-08-22T22:20:56Z
dc.date.accessioned2022-10-15T12:41:54Z
dc.date.available2019-08-22T22:20:56Z
dc.date.available2022-10-15T12:41:54Z
dc.date.created2019-08-22T22:20:56Z
dc.date.issued2009-06
dc.identifierAlcaraz, A. N.; Codnia, Jorge; Azcárate, María Laura; SiF4 IR Photodissociation: Gas phase reactions of SiF3 with CH4; Elsevier Science Sa; Journal of Photochemistry and Photobiology A: Chemistry; 205; 2-3; 6-2009; 79-83
dc.identifier1010-6030
dc.identifierhttp://hdl.handle.net/11336/82011
dc.identifierCONICET Digital
dc.identifierCONICET
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/4387297
dc.description.abstractThe infrared multiphoton dissociation (IRMPD) of SiF4 in the presence of CH4 has been studied using a tunable CO2 TEA laser. The siliconated reaction products have been identified. A kinetic scheme has been proposed to explain the experimental results. The reaction rate constant of the trifluorosilyl radical, SiF3, with CH4 has been obtained from the numerical solution of the differential equation system associated to the kinetic mechanism proposed as well as from non-linear regression methods. It has been additionally found that this reaction occurs through two channels. The relative importance of each and their reaction rate constants have been determined as well.
dc.languageeng
dc.publisherElsevier Science Sa
dc.relationinfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1010603009001488
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/https://doi.org/10.1016/j.jphotochem.2009.04.009
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.rightsinfo:eu-repo/semantics/restrictedAccess
dc.subjectINFRARED MULTIPHOTON DISSOCIATION
dc.subjectREACTION RATE
dc.subjectSILICON TETRAFLUORIDE
dc.subjectTRIFLUOROSILYL
dc.titleSiF4 IR Photodissociation: Gas phase reactions of SiF3 with CH4
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:ar-repo/semantics/artículo
dc.typeinfo:eu-repo/semantics/publishedVersion


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