info:eu-repo/semantics/article
N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
Fecha
2011-10Registro en:
Suarez, Sebastian; Foi, Maria Ana; Eady, Shawn; Larsen, Anna; Doctorovich, Fabio; N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C-Crystal Structure Communications; 67; 10; 10-2011; 417-420
0108-2701
CONICET Digital
CONICET
Autor
Suarez, Sebastian
Foi, Maria Ana
Eady, Shawn
Larsen, Anna
Doctorovich, Fabio
Resumen
The title compound, C 9H 14N +· CHB 11Cl 11 -, was obtained in the course of our continuing studies of the low-melting salts of closo- and nido-carborane cage anions with alkyl-pyridinium and dialkyl-imidazolium cations. The title compound is the first example of a pyridinium salt of a perchlorinated carborane anion. The structure consists of one N-butyl-pyridinium cation counterbalanced by one perchlorinated carborane cage anion per asymmetric unit. By changing the counter-ion, different packings are observed, and to try to understand this the new structure is compared with five similar compounds. © 2011 International Union of Crystallography.