info:eu-repo/semantics/article
Niobium-based semiconductor electrodes for hydrogen evolution reaction
Fecha
2019-11Registro en:
Franceschini, Esteban Andrés; Hainer, Andrew; Lanterna, Anabel Estela; Niobium-based semiconductor electrodes for hydrogen evolution reaction; Pergamon-Elsevier Science Ltd; International Journal of Hydrogen Energy; 44; 60; 11-2019; 31940-31948
0360-3199
CONICET Digital
CONICET
Autor
Franceschini, Esteban Andrés
Hainer, Andrew
Lanterna, Anabel Estela
Resumen
This contribution focusses on the use of Nb-based materials for the preparation of hybrid nickel-semiconductor electrodes for use in the electrochemical generation of hydrogen. The Nb-based semiconductors (i.e., Nb2O5 and Nb3(PO4)5) show good performance for the H2 evolution reaction (HER) using a non-toxic electrolyte (K2CO3) under true water-splitting conditions. Particularly, Nb2O5 shows HER efficiency two orders of magnitude higher than its TiO2 counterparts. Tafel analysis suggests the HER mechanism is the same for all type of electrodes studied and electrochemical impedance spectroscopy indicates these hybrid Ni–Nb-semiconductor electrodes are sensitive to light exposure, unlike TiO2. We propose that the differences in impedance upon irradiation are due to the band structure of these hybrid electrodes, which have lower Schottky barrier heights and show smaller work function values.