Catalytic reactivity of Cr/SiO2 in the liquid phase oxidation of cyclohexanol by tert-butyl hydroperoxide

Parentis, Monica Liliana; Bonini, Norberto Alejandro; Gonzo, Elio Emilio

info:eu-repo/semantics/article

Fecha

2002-03

Registro en:

Parentis, Monica Liliana; Bonini, Norberto Alejandro; Gonzo, Elio Emilio; Catalytic reactivity of Cr/SiO2 in the liquid phase oxidation of cyclohexanol by tert-butyl hydroperoxide; Springer; Reaction Kinetics And Catalysis Letters; 76; 2; 3-2002; 243-248

0133-1736

http://hdl.handle.net/11336/70722

CONICET Digital

CONICET

https://repositorioslatinoamericanos.uchile.cl/handle/2250/4366324

Autor

Parentis, Monica Liliana

Bonini, Norberto Alejandro

Gonzo, Elio Emilio

Institución

Consejo Nacional de Investigaciones Científicas y Tecnológicas (Argentina)

Resumen

Silica supported chromium is a heterogeneous, active and selective catalyst for the liquid phase oxidation of cyclohexanol by tert-butyl hydroperoxide (TBHP) in the presence or absence of oxygen. It is also active for the decomposition of TBHP. The reactivity at 70°C and atmospheric pressure is higher than over other catalysts and the cyclohexanone selectivity is 100%.

Materias

ALKYL HYDROPEROXIDE

CHROMIUM CATALYSTS

CYCLOHEXANOL OXIDATION

Mostrar el registro completo del ítem