A Theoretical Study of the Diels-Alder Reaction between 3-nitrofuran and Different Dienes Developed in Ionic Liquids

Cainelli, Mauro; Ormachea, Carla; Kneeteman, Maria Nelida; Mancini, Pedro Maximo Emilio

info:eu-repo/semantics/article

Fecha

2016-07

Registro en:

Cainelli, Mauro; Ormachea, Carla; Kneeteman, Maria Nelida; Mancini, Pedro Maximo Emilio; A Theoretical Study of the Diels-Alder Reaction between 3-nitrofuran and Different Dienes Developed in Ionic Liquids; ScienceDomain international; International Research Journal of Pure & Applied Chemistry; 12; 2; 7-2016; 1-10

2231-3443

http://hdl.handle.net/11336/69022

CONICET Digital

CONICET

https://repositorioslatinoamericanos.uchile.cl/handle/2250/4359240

Autor

Cainelli, Mauro

Ormachea, Carla

Kneeteman, Maria Nelida

Mancini, Pedro Maximo Emilio

Institución

Consejo Nacional de Investigaciones Científicas y Tecnológicas (Argentina)

Resumen

In this study the reactivity of 3-nitrofuran acting as electrophile in their reactions with different dienes, was analyzed in theoretical form. Specifically, the mechanism of each DA reaction was explored. Moreover, considering the polar character of this type of cycloaddition reaction we have discussed the modification of the dienophile reactivity when the solvent effect is considered by adding molecules of ILs to the dienophile optimizations.

Materias

NITROFURAN

DIELS-ALDER

THEORETICAL CALCULATIONS

MECHANISM

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