info:eu-repo/semantics/article
Transition metal- and organophotocatalyst-free perfluoroalkylation reaction of amino(hetero) aromatics initiated by the complex [(TMEDA)I$I3] and visible light
Fecha
2016-12Registro en:
Yerien, Damián Emilio; Conde, Romina Soledad; Camps, Bruno; Barata Vallejo, Sebastian; Lantaño, Beatriz; et al.; Transition metal- and organophotocatalyst-free perfluoroalkylation reaction of amino(hetero) aromatics initiated by the complex [(TMEDA)I$I3] and visible light; Royal Society of Chemistry; Royal Society of Chemistry Advances; 2017; 7; 12-2016; 266-274
2046-2069
CONICET Digital
CONICET
Autor
Yerien, Damián Emilio
Conde, Romina Soledad
Camps, Bruno
Barata Vallejo, Sebastian
Lantaño, Beatriz
Postigo, Jose Alberto
Resumen
Radical initiation for the perfluoroalkylation reaction of amino(hetero)aromatics has been accomplishedemploying the complex [(TMEDA)I$I3] and visible light. This methodology circumvents the use ofmetal(organo)catalysts and biologically-relevant substrates are easily substituted with RF moieties employinga mild and environmentally benign radical strategy starting from readily-available perfluoroalkyl iodides RFI.