Evaluation of the use of mandelate derivatives to determine the enantiomeric purity and the absolute configuration of secondary cyclohexenols

dc.creatorSarotti, Ariel Marcelo
dc.creatorPisano, Pablo Luis
dc.creatorPellegrinet, Silvina Carla
dc.date.accessioned2021-03-11T20:20:58Z
dc.date.accessioned2022-10-15T06:54:59Z
dc.date.available2021-03-11T20:20:58Z
dc.date.available2022-10-15T06:54:59Z
dc.date.created2021-03-11T20:20:58Z
dc.date.issued2011-03
dc.identifierSarotti, Ariel Marcelo; Pisano, Pablo Luis; Pellegrinet, Silvina Carla; Evaluation of the use of mandelate derivatives to determine the enantiomeric purity and the absolute configuration of secondary cyclohexenols; Arkat USA; Arkivoc; 2011; 7; 3-2011; 343-357
dc.identifier1551-7012
dc.identifierhttp://hdl.handle.net/11336/128129
dc.identifier1551-7004
dc.identifierCONICET Digital
dc.identifierCONICET
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/4357531
dc.description.abstractThe use of mandelate derivatives to determine the enantiomeric purity and the absolute configuration of isomeric mixtures of bicyclic and monocyclic secondary cyclohexenols was investigated. Synthesis, NMR and conformational analyses of the derivatives were performed and Gauge-Independent Atomic Orbital (GIAO) 1H NMR Boltzmann weighted average chemical shifts were computed. The studied methodology proved to be of practical value for most of the systems under study.
dc.languageeng
dc.publisherArkat USA
dc.relationinfo:eu-repo/semantics/altIdentifier/url/http://www.arkat-usa.org/arkivoc-journal/browse-arkivoc/2011/7/
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.3998/ark.5550190.0012.728
dc.rightshttps://creativecommons.org/licenses/by/2.5/ar/
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectABSOLUTE CONFIGURATION
dc.subjectENANTIOMERIC PURITY
dc.subjectMANDELATE DERIVATIVES
dc.subjectNMR SPECTROSCOPY
dc.subjectTHEORETICAL CALCULATIONS
dc.titleEvaluation of the use of mandelate derivatives to determine the enantiomeric purity and the absolute configuration of secondary cyclohexenols
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:ar-repo/semantics/artículo
dc.typeinfo:eu-repo/semantics/publishedVersion


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