| dc.creator | Sangermano, Marco | |
| dc.creator | Rodriguez, Damian | |
| dc.creator | Gonzalez, Monica Cristina | |
| dc.creator | Laurenti, Enzo | |
| dc.creator | Yagci, Yusuf | |
| dc.date.accessioned | 2020-03-16T20:09:46Z | |
| dc.date.accessioned | 2022-10-15T05:44:48Z | |
| dc.date.available | 2020-03-16T20:09:46Z | |
| dc.date.available | 2022-10-15T05:44:48Z | |
| dc.date.created | 2020-03-16T20:09:46Z | |
| dc.date.issued | 2018-07 | |
| dc.identifier | Sangermano, Marco; Rodriguez, Damian; Gonzalez, Monica Cristina; Laurenti, Enzo; Yagci, Yusuf; Visible Light Induced Cationic Polymerization of Epoxides by Using Multiwalled Carbon Nanotubes; Wiley VCH Verlag; Macromolecular Rapid Communications; 39; 13; 7-2018; 1-4 | |
| dc.identifier | 1022-1336 | |
| dc.identifier | http://hdl.handle.net/11336/99685 | |
| dc.identifier | CONICET Digital | |
| dc.identifier | CONICET | |
| dc.identifier.uri | https://repositorioslatinoamericanos.uchile.cl/handle/2250/4351264 | |
| dc.description.abstract | The visible light induced cationic polymerization of epoxides can be achieved by means of multiwalled carbon nanotubes (MWCNTs), which act as visible light photoinitiators via a radical-induced cationic photopolymerization process. When MWCNTs are irradiated with longer wavelengths (above 400 nm), they generate carbon radicals, by means of hydrogen abstraction from the epoxy monomer; these radicals are oxidized in the presence of iodonium salt to a carbocation that is sufficiently reactive to start the cationic ring-opening polymerization of an epoxy monomer. These mechanisms have been supported by electron paramagnetic resonance analysis. | |
| dc.language | eng | |
| dc.publisher | Wiley VCH Verlag | |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/https://doi.org/10.1002/marc.201800250 | |
| dc.relation | info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/full/10.1002/marc.201800250 | |
| dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | |
| dc.rights | info:eu-repo/semantics/restrictedAccess | |
| dc.subject | EPOXY MONOMERS | |
| dc.subject | MWCNTS | |
| dc.subject | VISIBLE LIGHT CATIONIC PHOTOPOLYMERIZATION | |
| dc.title | Visible Light Induced Cationic Polymerization of Epoxides by Using Multiwalled Carbon Nanotubes | |
| dc.type | info:eu-repo/semantics/article | |
| dc.type | info:ar-repo/semantics/artículo | |
| dc.type | info:eu-repo/semantics/publishedVersion | |
