info:eu-repo/semantics/article
Smart thermomechanochemical composite materials driven by different forms of electromagnetic radiation
Fecha
2020-01Registro en:
Riberi, Kevin Sebastián; Bongiovanni Abel, Silvestre Manuel; Martinez, María Victoria; Molina, María Alejandra; Rivarola, Claudia Rosana; et al.; Smart thermomechanochemical composite materials driven by different forms of electromagnetic radiation; Molecular Diversity Preservation International; Journal of Composites Science; 4; 1; 1-2020; 1-21
2504-477X
CONICET Digital
CONICET
Autor
Riberi, Kevin Sebastián
Bongiovanni Abel, Silvestre Manuel
Martinez, María Victoria
Molina, María Alejandra
Rivarola, Claudia Rosana
Acevedo, Diego Fernando
Rivero, Rebeca Edith
Cuello, Emma Antonia
Gramaglia, Romina Andrea
Barbero, César Alfredo
Resumen
Photo-thermo-mechanochemical (P-T-MCh) nanocomposites provide a mechanical and/or chemical output (MCh) in response to a photonic (P) input, with the thermal (T) flux being the coupling factor. The nanocomposite combines a photon absorbing nanomaterial with a thermosensitive hydrogel matrix. Conjugated (absorbing in the near infrared (NIR, 750–850 nm) wavelength range) polymer (polyaniline, PANI) nanostructures are dispersed in cross-linked thermosensitive (poly(N-isopropylacrylamide), PNIPAM) hydrogel matrices, giving the nanocomposite P-T-MCh properties. Since PANI is a conductive polymer, electromagnetic radiation (ER) such as radiofrequency (30 kHz) and microwaves (2.4 GHz) could also be used as an input. The alternating electromagnetic field creates eddy currents in the PANI, which produces heat through the Joule effect. A new kind of “product” nanocomposite is then produced, where ER drives the mechanochemical properties of the material through thermal coupling (electromagnetic radiation thermomechanochemical, ER-T-MCh). Both optical absorption and conductivity of PANI depend on its oxidation and protonation state. Therefore, the ER-T-MCh materials are able to react to the surroundings properties (pH, redox potential) becoming a smart (electromagnetic radiation thermomechanochemical) (sER-T-MCh) material. The volume changes of the sER-T-MCh materials are reversible since the size and shape is recovered by cooling. No noticeable damage was observed after several cycles. The mechanical properties of the composite materials can be set by changing the hydrogel matrix. Four methods of material fabrication are described.