info:eu-repo/semantics/article
The non-metathetic role of Grubbs’ carbene complexes: From hydrogen-free reduction of α,β-unsaturated alkenes to solid-supported sequential cross-metathesis/reduction
Fecha
2011-02Registro en:
Poeylaut Palena, Andrés Alberto; Testero, Sebastian Andres; Mata, Ernesto Gabino; The non-metathetic role of Grubbs’ carbene complexes: From hydrogen-free reduction of α,β-unsaturated alkenes to solid-supported sequential cross-metathesis/reduction; Royal Society of Chemistry; Chemical Communications; 47; 5; 2-2011; 1565-1567
1359-7345
CONICET Digital
CONICET
Autor
Poeylaut Palena, Andrés Alberto
Testero, Sebastian Andres
Mata, Ernesto Gabino
Resumen
An efficient and high-yielding “hydrogen-free” reduction of α,β-unsaturated alkenes was carried out employing Grubbs' catalyst in a non-metathetic role and Et3SiH. Conditions were optimized under microwave irradiation. Application to the solid-phase organic synthesis allows a facile construction of sp3–sp3 carbon bonds through a sequential cross metathesis/olefin reduction.