info:eu-repo/semantics/article
A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine
Fecha
2009-11Registro en:
Alborés, Pablo; Rentschler, Eva; A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine; Wiley VCH Verlag; Angewandte Chemie; 48; 49; 11-2009; 9366-9370
1433-7851
CONICET Digital
CONICET
Autor
Alborés, Pablo
Rentschler, Eva
Resumen
A record Co36 cluster is prepared. This mixed-valent compound containing CoII and CoIII centers is formed in the reaction of a dinuclear cobalt pivalate species with the polydentate 2,3-dicarboxypyrazine ligand. In terms of magnetic properties it behaves as a {Co16-Co16} supramolecular dimer in which the S = A spin ground states of each monomer do not interact.