Selective synthesis and molecular structure of novel aminooxyglycosyl derivatives bearing hydroxyphenyl moieties

Abstract

We present the selective synthesis of novel aminooxy glycosyl derivatives bearing hydroxy phenyl moieties. A strict control over the anomeric and E/Z configurations has been achieved. The products obtained are α-glycosides and the aromatic moiety substitute the Schiff's base trans to the O-glycosidic bond. Single crystal X-ray diffraction and NMR spectral data are reported and analysed.