info:eu-repo/semantics/article
Thermally Promoted Elimination and Substitution Reactions in Poly(p-arylene vinylene) Precursor Polyelectrolytes
Date
2000-06Registration in:
Garay, Raúl Oscar; Sarimbalis, Myrian N.; Hernandez, Sandra Analia; Montani, Rosana Silvia; Thermally Promoted Elimination and Substitution Reactions in Poly(p-arylene vinylene) Precursor Polyelectrolytes; American Chemical Society; Macromolecules; 33; 12; 6-2000; 4398-4402
0024-9297
CONICET Digital
CONICET
Author
Garay, Raúl Oscar
Sarimbalis, Myrian N.
Hernandez, Sandra Analia
Montani, Rosana Silvia
Abstract
The thermal conversion of dialkylsulfonium polyelectrolyte precursor polymers 1b-e to poly(p-arylene vinylene)s was studied by direct pyrolysis mass spectrometry in order to elucidate the mechanism of the sulfonium elimination reaction. The temperature dependence of the single ion currents of the four more abundant volatile products was correlated with the structural changes introduced in the arylene moiety of the polyelectrolytes and with the counterion nature. Experimental results suggest that the elimination reactions in the solid state proceed through an E2 mechanism.
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