info:eu-repo/semantics/article
Insight into the Metal Content–Structure–Property Relationship in Lanthanide Metal–Organic Frameworks: Optical Studies, Magnetism, and Catalytic Performance
Fecha
2018-06Registro en:
Gomez, Germán Ernesto; Brusau, Elena Virginia; Sacanell, Joaquin Gonzalo; Soler Illia, Galo Juan de Avila Arturo; Narda, Griselda Edith; Insight into the Metal Content–Structure–Property Relationship in Lanthanide Metal–Organic Frameworks: Optical Studies, Magnetism, and Catalytic Performance; Wiley VCH Verlag; European Journal of Inorganic Chemistry; 2018; 20; 6-2018; 2452-2460
1434-1948
CONICET Digital
CONICET
Autor
Gomez, Germán Ernesto
Brusau, Elena Virginia
Sacanell, Joaquin Gonzalo
Soler Illia, Galo Juan de Avila Arturo
Narda, Griselda Edith
Resumen
Two series of metal–organic frameworks (MOFs) based on a flexible ligand and trivalent lanthanides were obtained hydrothermally in order to explore their optical properties at low temperature, magnetism, and catalytic activity in relation to their structural features. A multisite analysis was performed according to the 4f–4f transitions. Moreover, the heterogeneous catalytic activity of the series was evaluated in one-pot cyanosilylation with benzaldehyde as substrate. Recyclability, structure conservation, and catalytic efficiency were also evaluated and compared with those of analogous compounds.