info:eu-repo/semantics/article
Metal–organic frameworks meet polymer brushes: enhanced crystalline film growth induced by macromolecular primers
Fecha
2017-08Registro en:
Rafti, Matias; Allegretto, Juan Alejandro; Segovia, Gustavo Manuel; Tuninetti, Jimena Soledad; Giussi, Juan Martín; et al.; Metal–organic frameworks meet polymer brushes: enhanced crystalline film growth induced by macromolecular primers; Royal Society of Chemistry; Materials Chemistry Frontiers; 1; 11; 8-2017; 1-5
2052-1537
CONICET Digital
CONICET
Autor
Rafti, Matias
Allegretto, Juan Alejandro
Segovia, Gustavo Manuel
Tuninetti, Jimena Soledad
Giussi, Juan Martín
Bindini, Elisa
Azzaroni, Omar
Resumen
We used poly-(3-sulfopropylmethacrylate) brushes as macromolecular 3D primers to promote heterogeneous nucleation and growth of archetypal ZIF-8 MOF thin films. The enhancement can be understood in terms of a high preconcentration of Zn2+ ions in the polymer brush; this leads to a rapid increase of nucleation sites in the primer.