info:eu-repo/semantics/article
Reversible S-S Bond Breaking and Formation in Disulfide-containing Dinuclear Complexes of Mn(I)
Fecha
2001-12Registro en:
Ruiz, Javier; Ceroni, Mario; Quinzani, Oscar Valentín; Riera, Víctor; Piro, Oscar Enrique; Reversible S-S Bond Breaking and Formation in Disulfide-containing Dinuclear Complexes of Mn(I); Wiley VCH Verlag; Angewandte Chemie; 40; 1; 12-2001; 220-222
0570-0833
CONICET Digital
CONICET
Autor
Ruiz, Javier
Ceroni, Mario
Quinzani, Oscar Valentín
Riera, Víctor
Piro, Oscar Enrique
Resumen
An isolated reaction intermediate in the desulfurization of thiones promoted by phosphanes is provided by the ylide derivative 3, which is obtained by thiophilic addition of PCy3 to 2. Complex 2 is formed from the disulfide‐containing dimetallic complex 1 by scission of the S−S bond. [Mn]=Mn(CO)4+, R=Ph.