Structure of a Luminescent MOF-2 Derivative with a Core of Zn(II)-Terephthalate-Isoquinoline and Its Application in Sensing of Xylenes

dc.creatorSánchez Mendieta, Víctor ; 13230
dc.creatorRosales Vázquez, Luis David;#0000-0002-9704-5146
dc.creatorBAZANY RODRIGUEZ, IVAN JONATHAN; 662748
dc.creatorHERNANDEZ ORTEGA, SIMON; 21880
dc.creatorVILCHIS NESTOR, ALFREDO RAFAEL; 161073
dc.creatorCAZARES MARINERO, JOSE DE JESUS; 256910
dc.creatorDORAZCO GONZALEZ, ALEJANDRO; 205445
dc.creatorSánchez Mendieta, Víctor
dc.creatorRosales Vázquez, Luis David
dc.creatorBAZANY RODRIGUEZ, IVAN JONATHAN
dc.creatorHERNANDEZ ORTEGA, SIMON
dc.creatorVILCHIS NESTOR, ALFREDO RAFAEL
dc.creatorCAZARES MARINERO, JOSE DE JESUS
dc.creatorDORAZCO GONZALEZ, ALEJANDRO
dc.date2021-02-26T01:01:00Z
dc.date2021-02-26T01:01:00Z
dc.date2020-04-27
dc.date.accessioned2022-10-13T00:07:57Z
dc.date.available2022-10-13T00:07:57Z
dc.identifier2073-4352
dc.identifierhttp://hdl.handle.net/20.500.11799/110150
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/4153677
dc.descriptionArticulo de investigación publicado en revista indexada.
dc.descriptionA new blue photoluminescent 2D metal–organic framework, 1, with formula {[Zn2( 2-BDC)2 (iQ)2]}1 has been synthesized in a high yield under solvothermal conditions by reacting Zn(II) ions with 1,4-benzenedicarboxylic acid (H2BDC) and isoquinoline (iQ) in DMF. Compound 1 was thoroughly characterized by single-crystal X-ray di raction, solid-state cross-polarization magic-angle spinning 13C NMR, X-ray powder di raction, scanning electron microscopy (SEM) with energy dispersive X-ray spectroscopy (EDS), and thermoanalysis. The crystal structure of 1 showed interpenetrated 2D frameworks consisting of dinuclear paddle-wheel cores Zn2; moreover, this material possessed thermostability up to 310 C. The CPMAS 13C-NMR spectrum of 1 is consistent with the symmetry of the crystal structure. Luminescence studies showed that 1 strongly enhances its fluorescence emission in the presence of xylene isomers with a pronounced selectivity to p-xylene.
dc.descriptionUniversidad Autónoma del Estado de México (Project 4995/2020CIB)
dc.languageeng
dc.publisherProf. Dr. Helmut Cölfen
dc.relation10
dc.relation2020
dc.relation10.3390/cryst10050344
dc.rightsopenAccess
dc.rightshttp://creativecommons.org/licenses/by-nc-nd/4.0
dc.subjectxylene isomers
dc.subjectfluorescent sensing
dc.subjectMOF-2 derivative
dc.subjectBIOLOGÍA Y QUÍMICA
dc.titleStructure of a Luminescent MOF-2 Derivative with a Core of Zn(II)-Terephthalate-Isoquinoline and Its Application in Sensing of Xylenes
dc.typeArtículo
dc.typearticle


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