dc.creatorNascimento, Rubens Maribondo do
dc.creatorRajesh, Surendran
dc.creatorMacedo, Daniel Araújo de
dc.creatorSouza, Graziele Lopes de
dc.creatorFigueiredo, Filipe Miguel Henriques Lebre Ramos
dc.creatorMarques, Fernando M. B.
dc.date2022-03-09T18:57:03Z
dc.date2022-03-09T18:57:03Z
dc.date2013-12-13
dc.identifierRAJESH, Surendran; MACEDO, Daniel A.; NASCIMENTO, Rubens M.; SOUZA, Graziele L.; FIGUEIREDO, Filipe M. L.; MARQUES, Fernando M. B. One-step synthesis of composite electrolytes of Eu-doped ceria and alkali metal carbonates. International Journal of Hydrogen Energy, [S.L.], v. 38, n. 36, p. 16539-16545, dez. 2013. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S036031991301286X?via%3Dihub. Acesso em: 08 abr. 2021. http://dx.doi.org/10.1016/j.ijhydene.2013.05.090.
dc.identifier0360-3199
dc.identifierhttps://repositorio.ufrn.br/handle/123456789/46476
dc.identifier10.1016/j.ijhydene.2013.05.090
dc.descriptionEuropium-doped ceria (EDC, Ce0.9Eu0.1O2 d)/alkaline carbonate (LNC, (Li,Na)2CO3) composite ceramics prepared through a one-step citrate-based route were analyzed by powder X-ray diffraction, infrared and laser Raman spectroscopies as well as scanning and transmission electron microscopy. The electrochemical behavior of the electrolyte material was studied by impedance spectroscopy in air, CO2 and N2 þ H2 (90/10 vol%, respectively) gas mixtures, in the temperature range 300e600 C. The sub micrometric and even nanosized ceramic particles appeared as merged inside the mixed carbonates, with modest grain to grain necking. The EDC/LNC composite electrolytes showed a conductivity of 0.27 S cm 1 at 600 C in air, amongst the best ever reported, exceeding the usual requirements for fuel cell applications
dc.languageen
dc.publisherElsevier
dc.subjectComposite electrolytes
dc.subjectCeria
dc.subjectElectrical conductivity
dc.subjectOne-step synthesis
dc.titleOne-step synthesis of composite electrolytes of Eu-doped ceria and alkali metal carbonates
dc.typearticle


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